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Materialia Indica

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Metallurgical Thermodynamics: Problems and Solutions


  • How does the internal energy change in an isothermal process?
  • Where does the entire supplied heat go in isochoric and isothermal processes?
  • What is an isentropic process?
  • Derive the Clausius-Clapeyron equation.
  • Find the expression that relates Cp and Cv using Maxwell's relations.
  • What does the rate of change of Gibb's free energy with respect to pressure at constant temperature give you?
  • Prove the following expressions using Maxwell's relations:

    1. dV = V{alpha}dT - V{beta}dP
    2. dS = {Cp/T}dT - V{alpha}dP








































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